Please read before you post... There is a thread in here somewhere where someone posted a few builds usable to defeat doppleganger, in the same thread I gave a smiting build capable of defeating him in under 20 seconds.
I would just type the build, but I don't have time (sorry if I seemed rude initially)... Look up the build and you should be fine.
...You could try a variation of my smiting build and just use Fire Magic DoT AoEs on him (smiting is SoW + Balth Aura + Zealot's Fire + Spam of Prot Spirit and Reversal...works every time with Blessed Sig + Balth Spirit + Essence Bond + [the one that makes your enchantments last longer goes here]).
Fire would likely use Meteor Shower + Firestorm + Searing Heat (if you have energy for all 3, otherwise just Fstorm + Searing + Symbol of Wrath [only costs 5e])
Anyway, good luck.
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